DESCRIPTION OF PROCESS IN AQUEOUS SOLUTIONS: DIFFERENCES BETWEEN XIX AND XX CENTURIES CONCEPTIONS
DOI:
https://doi.org/10.18540/jcecvl5iss1pp0020-0025Keywords:
Aqueous Solution, Chemical Equibria, Misconceptions / Discrepant Events, Chemical EquationAbstract
The development of studies of Chemical solutions occurred with two distinct concepts, the XIX century concept, and the XX century concept. XIX century concept was created before the Arrhenius’ electrolytic theory and it did not consider the real chemical species in solution. The differences between these concepts can seem subtle at a glance, but some examples are shown to clarify them, as well as the problems with use the XIX century concept. The examples involve differences in chemical equations, Henderson-Hasselbach Equation, Arrhenius’ Ionization degree, Acid-base and solubility equilibria.Downloads
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References
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14. PO, H. N., J. Chem.Ed., 2001, (78) 1499-1503; Levie, R.Chem.Educator, 2002, (7) 132-135.
15. KOLTHOFF, I.M., Acid-Base Indicators, (1937) MacMillan, N.York
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2. BROWN, T. E.; LEMAY, H. E. H.; BURSTEN, B. E.; WOODWARD, P.;MURPHY, C. Chemistry The Central Science, 12th ed.; Prentice Hall: NY, 2011.
3. KOTZ, J.C.; TREIC HEL, P.M.;TOWNSEND, J.R., Chemistry & Chemical Reactivity, 8th ed., Cengage Learning: Belmont, 2012.
4. SZABADRARY, F. C., History of Analytical Chemistry Pergamon Press, Oxford, 1996; PARTINGTON, J.R., History of chemistry, St Martin Press: N. York, 1961.
5. MACINNES, D. A., The Principles of Electrochemistry, Reinhold Publishing Co.: N.Y, 1939.
6. HALL, F. N., J.Chem.Ed., 1940, 124.
7. FRANKLIN, E.C.; J.Am.Chem.Soc.46,1924, 2437; GERMANN, A.F.O Science 1921, 582.; GERMANN, A.F.O J. Am.Chem.Soc. 1925, 47, 2461.; FRANKLIN E.C.; J. Am. Chem. Soc., 1924, 46, 2137.
8. MCCUTCHEON, T.P; SELTZ, H; WARNER, J.C. General Chemistry, 3rd ed.;Van Nostrand : NYork, 1939.
9. DEAN, D.A., Lange’s Handbook, 15th ed., CRC: Boca Raton, 1999.
10. MARX, D.; TUCKERMAN, M.E.; PARRINELLO, J.H.M, Nature, 397, 601-604.
11. VENER, M.V.; LIBROVICH, N.B., Journal International Reviews in Physical Chemistry Volume 28, 2009 (3),407-434
12. OLIVEIRA, A. F., Equilíbrio Químico em Solução Aquosa (Chemical Equilibrium in Aqueous Solution) Editora Átomo: Campinas, 2009. (in portuguese)
13. HARRIS, D. C. Quantitative Chemical Analysis, 8th edition, W.H.Freeman &Co: N.York, 2010.
14. PO, H. N., J. Chem.Ed., 2001, (78) 1499-1503; Levie, R.Chem.Educator, 2002, (7) 132-135.
15. KOLTHOFF, I.M., Acid-Base Indicators, (1937) MacMillan, N.York
16. VOGEL, A. I. SVEHLA,G., Vogel’s Macro and semimicro qualitative inorganic analysis, 5th ed. Longman Group: London. 605 pp.
17. PAIK, S-H, J. Chem. Educ., 2015, 92 (9), 1484–1489
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Published
2019-03-08
How to Cite
Oliveira, A. F., Pereira, R. L., Flores Jr, M., Neves, A. A., & Queiroz, M. E. L. R. (2019). DESCRIPTION OF PROCESS IN AQUEOUS SOLUTIONS: DIFFERENCES BETWEEN XIX AND XX CENTURIES CONCEPTIONS. The Journal of Engineering and Exact Sciences, 5(1), 0020–0025. https://doi.org/10.18540/jcecvl5iss1pp0020-0025
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Engineering Education and Science Education
