STUDY OF BIODIESEL PRODUCTION BY HETEROGENEOUS CATALYSIS USING MAGNETIC NANOPARTICLES SUPPORTED IN SILICA IN A PACKED BED REACTOR

Autores

  • Allan Boury Centro Universitário da FEI
  • Andeson Zussa
  • Christian Campos
  • Marta Felix
  • Mariana Felix
  • Maristhela Marin
  • Luis Ferreira
  • Newton Ferreira
  • Sergio Toma
  • Marcos Toyama

DOI:

https://doi.org/10.18540/jcecvl5iss1pp0137-0142

Palavras-chave:

Packed Bed Reactor, Nanoparticle, silica, Transesterification

Resumo

In this work the biodiesel production was studied through heterogeneous catalysis using SPIONs in silica. The reaction was conducted in a fixed bed reactor immersed in thermostated bath to maintain the temperature at 60 °C using 1:6:5 (soybean/methanol/tert-butanol) molar ratios between reagents and reaction times of 6,8 and 10 hours. The reactions were also conducted in Erlenmeyer incubators at Shaker under the same conditions of molar ratios and temperature, with agitation of 300 rpm, samples being withdrawn from time to time ranging from 0.25 to 8 hours. The results showed that when the reaction was conducted in a fixed bed reactor the best conversion was achieved in batch of 10 hours being equal to 3.18% and that when incubated in Shaker a conversion of 36.04% in 8 hours. In this study the kinetic constant was also determined from the experiments incubated at Shaker and proposed a transesterification process model using the ASPEN PLUS (R) process simulator.

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Biografia do Autor

Allan Boury, Centro Universitário da FEI

Possui graduação em Engenharia Química pela Universidade Estadual do Oeste do Paraná – UNIOESTE (2003); Mestrado em Engenharia Química na área de desenvolvimento de processos químicos pela Universidade Estadual de Campinas DPQ/FEQ/UNICAMP (2007); Capacitação em Gerenciamento de Projetos pela Universidade Estadual de Campinas – UNICAMP (2008) e Doutorado em Engenharia Química pela Faculdade de Engenharia Química da Universidade Estadual de Campinas – UNICAMP (2012). Atuou de 2012 a 2014 como pesquisador colaborador no LCAP: Laboratório de Controle e Automação de Processos, DESQ/FEQ/UNICAMP e de 2014 a 2015 como Professor Doutor I MS3.1 na Faculdade de Engenharia de Alimentos da UNICAMP. Atualmente é Professor Adjunto I no Centro Universitário da FEI e pesquisador colaborador no LCAP/ DESQ/FEQ/UNICAMP. Tem experiência na área de Engenharia Química, com ênfase em Reatores Poliméricos, Modelagem e Simulação e Controle e Automação, atuando principalmente nos seguintes temas: polimerização via radical livre controlado, RAFT, Comunicação OPC, CLP, refrigeração industrial, IA (lógica fuzzy e neuro-fuzzy e redes neurais), Identificação de Sistemas, Controle e instrumentação.


Referências

BORGES, M.B; DÍAZ, L. Catalytic Packed-Bed Reactor ConFiguration for BiodieselProduction Using Waste Oil as Feedstock. BioEnergy Research, v. 6, p. 222-228, 2012.

CARVALHO, J.F.D. Combustíveis fósseis e insustentabilidade. Ciência e cultura. v. 60, n.3. São Paulo, 2008.

FERREIRA, H. S.; RANGEL, M., Nanotecnologia: aspectos gerais e potencial de aplicação em catálise. Quim. Nova, Vol. 32, No. 7, 1860-1870, 2009.

FREEDMAN, B.; BUTTERFIELD, R. O.; PRYDE, E. H. Transesterification kinetics of soybean oil. Journal of the American oil chemists’ society, vol. 63, issue 10, p. 1375-1380, 1986.

HASHMI, S., GOHAR, S., MAHMOOD, T., NAWAZ, U., FAROOQI, H.; Biodiesel Production by using CaO-Al2O3 nano catalyst, International Journal of Engineering Research & Science, vol.2, issue 3, 43-49, 2016

IVANA B. BANKOVIC-ILIC, MARIJA R. MILADINOVIC, OLIVEIRA S. STAMENKOVIC, VLADA B. VELJKOVIC, Application of nano CaO-based catalysts in biodiesel synthesis, Renewable and Sustainable Energy Reviews, 72, 746-760, 2017.

JIANBING, JI et al. Preparation of biodiesel with the help of ultrasonic and hydrodynamic cavitation. Ultrasonics, v. 44, p. 411-414, 2006.

KNOTHE, G. The Biodiesel Handbook, Second Edition. Editora AOSC, Illinois, EUA, 2010.

MACALA, S.; ROBERTSON, W.; JOHNSON, C. L.; DAY, Z. B.; LEWIS, R. S.; WHITE, M. G.; IRETSKII, A. V., FORD, P. C. Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Produtction. Catal Letters, 122, p.205-209, 2008.

MADHUVILAKKU, R; PIRAMAN, S.; Biodiesel synthesis by TiO2-ZnO mixed oxide nanocatalyst catalyzed palm oil transesterification process, Bioresource Technology, 150, 55-59, 2013.

MANSIR, N.; YUN HIN TAUFIQ-YAP; RASHID, U.; LOKMAN, I. M.; Investigation of heterogeneous solid acid catalyst performance on low grade feedstock for biodiesel production: A review; Energy Conversion and Management, 141, 171-182, 2017.

MUSA, I. A., The effects of alcohol to oil molar ratios and type of alcohol on Biodiesel production using transesterification process, Egyptian Journal of Petroleum, v.25, issue 1, p. 21-31, 2016.

OLIVEIRA, F. C. C.; SUAREZ, P. A. Z.; SANTOS, W. P.D; Biodiesel: Possibilidades e Desafios. Química e Sociedade, v. 28, maio, São Paulo, 2008.

PAIVA, E.J.M. Estudo da produção de Biodiesel a partir de Óleo de Babaçu e Etanol utilizando a Transesterificação Alcalina Tradicional com Agitação Mecânica e Assistida por Ultrassons. 2010. 173 f. Dissertação (Mestre em Ciências) – Universidade de São Paulo, Lorena, 2010.

PRADANA, Y.S et al. Biodiesel production in a reactive distillation collumn catalyzes by heterogeneous potassion catalyst, Energy Procedia, v. 143, p.742-747, 2017.

RAMOS, L. P et al. Tecnologias de Produção de Biodiesel. Virtual Quim., v. 3, n. 5, p. 385-405, 2011.

ROTHENBERG, G. Catalysis, concepts and green applications. Índia: Wiley-Vch, 2008. p.12-17

SHI, WEI; ZHAO, JING; YUAN, XING; WANG, SHENGTIAN; WANG, XIAOHONG; HUO, MINGXIN; Effects of Bronsted and Lewis Acidities on Catalytic of Heteropolyacids in Transesterification and Esterification Reactions, Chem. Eng. Technol., 35, No. 2, 347-352, 2012.

SCHUCHARDT, U.; SERCHELI, R.; VARGAS, R. M. Transesterification of Vegetable Oils: A Review. Journal of the Brazilian Chemical Society, v. 9, n. 3, 1998.

SHARMA, R. K; YADAV, M; GAWANDE, M. B. Ferrites and Ferrates: Chemistry and Applications in Sustainable Energy and Environmental Remediation.Capítulo 1: Silica-Coated Magnetic Nano-Particles: Application in Catalysis 2018.

SUZUTA, T. et al. Iron Oxide Catalysts Supported on Porous Silica for the Production of Biodiesel from Crude Jatropha Oil. J Am Oil Chem Soc., v. 89, n. 11, p. 1981-1989, 2012.

VERMA, P; SHARMA, M.P., Review of process parameters for Biodiesel production from different feedstock, Renewable and Sustainable Energy Reviews, 62, 1063-1071, 2016.

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Publicado

2019-03-08

Como Citar

Boury, A., Zussa, A., Campos, C., Felix, M., Felix, M., Marin, M., Ferreira, L., Ferreira, N., Toma, S., & Toyama, M. (2019). STUDY OF BIODIESEL PRODUCTION BY HETEROGENEOUS CATALYSIS USING MAGNETIC NANOPARTICLES SUPPORTED IN SILICA IN A PACKED BED REACTOR. The Journal of Engineering and Exact Sciences, 5(1), 0137–0142. https://doi.org/10.18540/jcecvl5iss1pp0137-0142

Edição

Seção

Biotechnological Processes

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